There is a setting that you can change from your New Tab which hides the most visited sites from the New Tab. Therefore, there are two options for the user you can either disable the algorithm through which these sites are located or use an extension.
It isn’t that convenient to hide the most visited pages on a new tab because certain settings have been disabled in the newer versions of Chrome which prevent the user from doing so.
How to Hide Most Visited Pages on a New Tab on Chrome?